Englishpained
adjective
she stared at Hebden with a pained expression on her face:
upset, hurt, wounded, injured, insulted, offended, aggrieved, affronted, displeased, distressed, disgruntled, put out, annoyed, angered, angry, cross, exasperated, indignant, irritated, vexed, piqued, irked, stung, galled, nettled, needled, peeved, ruffled, resentful, in a huff, huffy, in high dudgeon, fed up;
informal riled, miffed, rattled, aggravated, peed off, hacked off;
British, informal narked, eggy, cheesed off, browned off, brassed off, not best pleased;
North American, informal teed off, ticked off, sore;
dated miffy, snuffy;
vulgar slang pissed off.
pained Oxford Dictionary of English